Pioneer Synthesis and Characterization of Boron Containing Hard Materials
نویسندگان
چکیده
The first laboratory synthesis of hard materials such as diamond proceeded to attack of developing materials with high hardness to compete diamond. Boron rich solids are good candidates owing to their short interatomic bond lengths and strong covalent character. Boron containing hard material was synthesized by modifiedmicrowave method under nitrogen atmosphere by using a fuel (glycine or urea), amorphous boron and/or boric acid in appropriate molar ratio. Characterizations were done by x-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy/energy dispersive analyze (SEM/EDS), thermo gravimetric/differential thermal analysis (TG/DTA). Keywords—Boron containing materials, hard materials, microwave synthesis, powder X-ray diffraction.
منابع مشابه
Synthesis and Characterization of a Novel Fe3O4-SiO2@Gold Core-Shell Biocompatible Magnetic Nanoparticles for Biological and Medical Applications
Objectives: The study of core-shell magnetic nanoparticles has a wide range of applications because of the unique combination of the nanoscale magnetic core and the functional shell. Characterization and application of one important class of core-shell magnetic nanoparticles (MNPs), i.e., iron oxide core (Fe3O4/γ-Fe2O3) with a silica shell and outer of gold (Fe3O4-SiO2@Gold (FSG)) in Boron Neut...
متن کاملHigh-Pressure Design of Advanced BN-Based Materials.
The aim of the present review is to highlight the state of the art in high-pressure design of new advanced materials based on boron nitride. Recent experimental achievements on the governing phase transformation, nanostructuring and chemical synthesis in the systems containing boron nitride at high pressures and high temperatures are presented. All these developments allowed discovering new mat...
متن کاملSynthesis and Characterization of PMMA with 4 - Carbazole Chromophore Substitution
A new carbazole- containing polymer has been synthesized for further photophysical studies. Efficient synthesis of the substituted methyl methacrylate has been accomplished via microwave assisted synthesis of 1 - chloro - 4-carboxy -5,6, 7, 8- tetrahydrocarbazole followed by further steps, such as reduction of the 4-substituted methyl carboxylate, dechlor...
متن کاملSynthesis and properties evaluation of TiB2 nanoparticles produced by sol-gel method
In this study, TiB2 particles were synthesized by sol-gel method in nanometer size. First, the sol was prepared in a four-component system of alkoxide -boron carbide -water-alcohol based on the sol-gel chemical process under acidic conditions at pH = 5. Titanium tetra-isopropoxide and boron carbide were used as raw materials. After hydrolysis and gel formation followed by heat treatment, TiB2 n...
متن کاملSynthesis of Boron Nitride powder by carbothermal method, using phenolic resin and carbon black and investigating the effect of additive of calcium carbonate
Effect of CaCO3 on carbothermic formation of hexagonal boron nitride (h-BN) was investigated. B2O3–C mixtures containing CaCO3 additive were reacted at 1500 for 120 min in nitrogen atmosphere. Formed phases in the reaction products were determined by powder-XRD analyses, and amounts of the constituents were determined by chemical analyses. Particle size and morphology of the formed h-BN powde...
متن کامل